This paper presents a statistical method for modelling the behaviour of household occupants to estimate residential energy consumption. Using data gathered by the U.S. Census Bureau in the American Time Use Survey (ATUS), actions carried out by survey respondents are categorized into ten distinct activities. These activities are defined to correspond to the major energy consuming loads commonly found within the residential sector. Next, time varying minute resolution Markov chain based statistical models of different occupant types are developed. Using these behavioural models, individual occupants are simulated to show how an occupant interacts with the major residential energy consuming loads throughout the day. From these simulations, the minimum number of occupants, and consequently the minimum number of multiple occupant households, needing to be simulated to produce a statistically accurate representation of aggregate residential behaviour can be determined. Finally, future work will involve the use of these occupant models alongside residential load models to produce a high-resolution energy consumption profile and estimate the potential for demand response from residential loads.